One-dimensional coordination polymers: Applications to material science
نویسندگان
چکیده
منابع مشابه
One-dimensional electrical contact to a two-dimensional material.
Heterostructures based on layering of two-dimensional (2D) materials such as graphene and hexagonal boron nitride represent a new class of electronic devices. Realizing this potential, however, depends critically on the ability to make high-quality electrical contact. Here, we report a contact geometry in which we metalize only the 1D edge of a 2D graphene layer. In addition to outperforming co...
متن کاملHeat-induced formation of one-dimensional coordination polymers on Au(111): an STM study.
The formation of one-dimensional coordination polymers of cyano-substituted porphyrin derivatives on Au(111) induced by thermal annealing is demonstrated by means of scanning tunnelling microscopy. The polymer is stabilised by an unusual threefold coordination motif mediated between an Au atom and the cyano groups of the porphyrin derivatives.
متن کاملOne-dimensional coordination polymers of antiferromagnetically-coupled [Mn4] single-molecule magnets.
Reactions of the rhombic [MnII2 MnIII2 (hmp)6]4+ complex in acetonitrile with simple carboxylate ligands yield (i) three new isolated [Mn4] complexes, namely [Mn4(hmp)6(CH3COO)2(H2O)2](ClO4)2.4H2O (1), [Mn4(hmp)6(CCl3COO)2(H2O)2](ClO4)2 (2) and [Mn4(hmp)6(C6H5COO)2(H2O)2](ClO4)2.4CH3CN.2H2O (3) in the presence of either bulky carboxylate or of an excess of Mn(II) source; and (ii) two 1D arrange...
متن کاملOne- and Two- Dimensional Copper(I) Halide Based Coordination Polymers with Bridging Pyridazine or Pyrimidine Ligands
Z. Naturforsch. 54 b, 1175-1180 (1999); received June 9, 1999 Copper(I) Halides, Pyridazine, Pyrimidine, Coordination Polymers 1-Dimensional coordination polymers J. [CuX(/i-pydz)] 1 3 (X = Cl, Br, I; pydz = pyrid azine) may be prepared by self-assembly in acetonitrile solution at 120 °C (1) or room temper ature (2, 3). Individual chains contain (CuX)2 rings and dimeric [Cu(^-pydz) ] 2 substr...
متن کاملProton dynamics of two-dimensional oxalate-bridged coordination polymers.
A two-dimensional porous coordination polymer (NH4)2{HOOC(CH2)4COOH}[Zn2(C2O4)3] (abbreviated as (NH4)2(adp)[Zn2(ox)3] (adp = adipic acid, ox = oxalate)), which accommodates water molecules between the [Zn2(ox)3] layers, is highly remarked as a new type of crystalline proton conductor. In order to investigate its phase behavior and the proton conducting mechanism, we have performed adiabatic ca...
متن کاملذخیره در منابع من
با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید
ژورنال
عنوان ژورنال: Coordination Chemistry Reviews
سال: 1993
ISSN: 0010-8545
DOI: 10.1016/0010-8545(93)80036-5